Equilibrium and kinetic models for colloid release under transient solution chemistry conditions
نویسندگان
چکیده
منابع مشابه
Equilibrium and kinetic models for colloid release under transient solution chemistry conditions.
We present continuum models to describe colloid release in the subsurface during transient physicochemical conditions. Our modeling approach relates the amount of colloid release to changes in the fraction of the solid surface area that contributes to retention. Equilibrium, kinetic, equilibrium and kinetic, and two-site kinetic models were developed to describe various rates of colloid release...
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Saturated packed column and micromodel transport studies were conducted to gain insight on mechanisms of colloid retention and release under unfavorable attachment conditions. The initial deposition of colloids in porous media was found to be a strongly coupled process that depended on solution chemistry and pore space geometry. During steady state chemical conditions, colloid deposition was no...
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This research compared the influence of (1) dissolution of iron oxides and (2) alteration of electrostatic interactions on the mobilization of colloids in a clayand iron oxidecoated sand obtained from an Atlantic Coastal Plain aquifer in which colloids have been found suspended only in anoxic groundwater. The sediment was flushed with solutions of varying ionic strength, pH, and reductant and s...
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[1] Contaminant-scavenging colloids are mobilized in the vadose zone during infiltration events, characterized by transient flow regimes. In the research reported here we develop a mathematical model in order to investigate the influences of flow transients on colloid mobilization in unsaturated media. The model solves coupled equations for unsteady pore water flow, colloid release, advective-d...
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ژورنال
عنوان ژورنال: Journal of Contaminant Hydrology
سال: 2015
ISSN: 0169-7722
DOI: 10.1016/j.jconhyd.2015.04.003